A method for forming a strained metal nitride film and a semiconductor
device containing the strained metal nitride film. The method includes
exposing a substrate to a gas containing a metal precursor, exposing the
substrate to a gas containing a nitrogen precursor activated by a plasma
source at a first level of plasma power and configured to react with the
metal precursor with a first reactivity characteristic, and exposing the
substrate to a gas containing the nitrogen precursor activated by the
plasma source at a second level of plasma power different from the first
level and configured to react with the metal precursor with a second
reactivity characteristic such that a property of the metal nitride film
formed on the substrate changes to provide the strained metal nitride
film.