The present invention is to provide a polymer electrolyte material capable of causing interaction with a hydrocarbon polymer electrolyte and ensuring bonding ability between a polymer electrolyte membrane and a catalyst layer as well as having excellent gas permeability, and a membrane electrode assembly for fuel cell using the same. A polymer electrolyte material comprises at least a first repeating unit containing a Si--O bond which forms a main backbone and a second repeating unit containing an aromatic ring and a proton-conducting group, and a membrane electrode assembly for fuel cell comprises a polymer electrolyte membrane and/or a catalyst layer containing the polymer electrolyte material.