Process for the manufacture of 1,2-dichloroethane starting with a
hydrocarbon source according to which: a) the hydrocarbon source is
subjected to cracking which produces a mixture of products containing
ethylene and other constituents; b) the said mixture of products is
separated into a fraction enriched with compounds which are lighter than
ethylene, containing part of the ethylene (fraction A), into a fraction
enriched with ethylene (fraction B) and into a heavy fraction (fraction
C); c) fraction A is conveyed to a chlorination reactor and fraction B to
an oxychlorination reactor, in which reactors most of the ethylene
present in fractions A and B is converted to 1,2-dichloroethane; d) the
1,2-dichloroethane obtained is separated from the streams of products
derived from the chlorination and oxychlorination reactors.