Environmentally safe, cost effective, VOC-free compositions and methods for the prevention and treatment of corrosive processes in and on metal such as rust, flash rust and scale in a wide variety of industry sectors is provided. Compositions particularly well-suited for the long term prevention of rust and other corrosive processes may include an organic acid or salt thereof, a natural gum and/or wax and/or extracts or derivatives thereof, a gelling agent, and water.