A method of protecting steel in concrete is disclosed. It consists of connecting the steel (6) to a discrete sacrificial anode assembly (7) comprising a base metal (1), a relatively small quantity of catalytic activating agent in contact with the base metal and a substantially inert porous layer (3) that surrounds the base metal and catalytic activating agent. The inert porous layer efficiently maintains a sustainable concentration gradient of the catalytic activating agent between the base metal and the surrounding environment as a result of the electric field across this layer. The preferred porous layer comprises a material that exhibits a net repulsion of negative ions from its pore system and the preferred catalytic activating agent comprises doubly charged sulphate ions as small electric fields maintain very high concentration gradients of these ions resulting in high concentrations at the base metal surface and insignificant concentrations at the assembly periphery.