A catalyst for selective hydrogenation of acetylenes and diolefins,
particularly in a raw gas feed stream for front end selective
hydrogenation. The catalyst contains a low surface area carrier with a
surface area from about 2-20 m2/g, wherein the pore volume of the pores
of the carrier is greater than about 0.4 cc/g, at least 90 percent of the
pore volume of the pores is contained within pores having a pore diameter
greater than about 500 .ANG. and about 1 to about 2 percent of the total
pore volume is contained in pores with a pore diameter from about 500 to
about 1,000 .ANG.. The palladium comprises about 0.01 to about 0.1 weight
% and a Group IB metal comprises about 0.005 to about 0.06 weight % of
the catalyst.