To provide a photomask cleaning method which brings about a high effect of
removing residual sulfuric acid or foreign objects and can remove foreign
objects effectively without fluctuating the transmission or other
properties of the light-shielding layer (MoSiON film) in a phase shift
photomask.
A method of cleaning a photomask which comprises a first step of cleaning
the surface of a photomask used as a master in the photolithography step
in the process for the production of semiconductor device with a hot
mixture of sulfuric acid and hydrogen peroxide to decompose organic
objects present thereon and remove metallic impurities, a second step of
removing residual sulfuric acid from the surface of said photomask, a
third step of removing foreign objects attached to the surface of said
photomask, and a fourth step of drying said photomask which has finished
with said first, second and third steps, characterized in that said second
step involves the removal of residual sulfuric acid from the surface of
said photomask with anodic water and said third step involves the removal
of foreign objects with cathodic water.