Novel latex or emulsion compositions containing internally plasticizing and
crosslinkable monomers derived from traditional semi-drying or non-drying
oils are disclosed and claimed. The monomers are ethylenically unsaturated
derivatives of long-chain olefinic compounds. Preferred embodiments
include latex formed from acrylate or methacrylate esters of fatty
alcohols. A process for the synthesis of the latex composition is also
disclosed, which involves (a) polymerization of the ethylenically
unsaturated derivatives of a long-chain olefinic compound in an aqueous
phase with at least one other copolymerizable monomer; and (b) blending of
so formed polymer with at least one drier and a surfactant to form the
novel latex or emulsion compositions. These compositions form films at low
minimum film forming temperatures (MFT) ranging from -5 to 10.degree. C.
and cure to above ambient glass transition (T.sub.g) polymers without the
use of traditional organic cosolvents which contribute to environmental
pollution via volatile organic compounds (VOCs) emissions. These
compositions are therefore useful in waterborne coatings, contact and
pressure sensitive adhesives, and inks.