A liquid precursor for forming a transparent metal oxide thin film
comprises a first organic precursor compound. In one embodiment, the
liquid precursor is for making a conductive thin film. In this embodiment,
the liquid precursor contains a first metal from the group including tin,
antimony, and indium dissolved in an organic solvent. The liquid precursor
preferably comprises a second organic precursor compound containing a
second metal from the same group. Also, the liquid precursor preferably
comprises an organic dopant precursor compound containing a metal selected
from the group including niobium, tantalum, bismuth, cerium, yttrium,
titanium, zirconium, hafnium, silicon, aluminum, zinc and magnesium.
Liquid precursors containing a plurality of metals have a longer shelf
life. The addition of an organic dopant precursor compound containing a
metal, such as niobium, tantalum or bismuth, to the liquid precursor
enhances control of the conductivity of the resulting transparent
conductor. In a second embodiment, a liquid precursor for forming a
transparent metal oxide nonconductive thin film comprises an organic
precursor compound containing a metal from the group including cerium,
yttrium, titanium, zirconium, hafnium, silicon, aluminum, niobium,
tantalum, and bismuth. Liquid precursors of the invention preferably
comprise a metal organic precursor compound, such as an ethylhexanoate, an
octanoate, or a neodecanoate, dissolved in a solvent, such as xylenes,
n-octane and n-butyl acetate.