A process of transferring a protection layer from a dye-donor receiver after thermal dye transfer. In one embodiment, the transferable protection layer contains inorganic particles, a polymeric binder, organic particles and an organic gloss-enhancing agent that enhances the gloss of the final print. The transferred protection layer that provides a higher gloss to an image after transfer. A laminate containing such a gloss-enhancing agent has been found to enable printing at lower line times, faster printing, for thermal prints withwhile maintaining high gloss.