Compositions for reduction of gas phase reduced nitrogen species and
NOx generated during a partial or incomplete combustion catalytic cracking
process, preferably, a fluid catalytic cracking process, are disclosed. The compositions
comprise (i) an acidic metal oxide containing substantially no zeolite, (ii) an
alkali metal, alkaline earth metal, and mixtures thereof, (iii) an oxygen storage
component, and (iv) a noble metal component, preferably rhodium or iridium, and
mixtures thereof, are disclosed. Preferably, the compositions are used as separate
additives particles circulated along with the circulating FCC catalyst inventory.
Reduced emissions of gas phase reduced nitrogen species and NOx in an
effluent off gas of a partial or incomplete combustion FCC regenerator provide
for an overall NOx reduction as the effluent gas stream is passed from
the FCC regenerator to a CO boiler, whereby as CO is oxidized to CO2 a
lesser amount of the reduced nitrogen species is oxidized to NOx.