A call processing method during terminating BUSY states (busy, power down, and paging failure) of a terminal in a radio intelligent network system. The method includes detecting the terminating BUSY state of the terminal from an HLR (Home Location Register); performing an OBUSY operation between a SCP and a T_Busy DP in a T_SSP when the terminating BUSY state is detected; generating an O_BCSM as a result of the operation; and re-attempting a call connect to a termination switch number transmitted to the generated O_BCSM.