Self-curable water-based solid adhesives of this invention include the
following components (A), (B), (C), and (D): (A) an
anionic-group-containing polymer terminally having an alkoxysilyl group,
the polymer being a reaction product of a compound (A1) containing no
anionic group and having plural isocyanate-reactive groups, a compound
(A2) having an anionic group and plural isocyanate-reactive groups, a
polyisocyanate compound (A3), and an alkoxysilane compound (A4)
containing an isocyanate-reactive group; (B) a basic compound; (C) water;
and (D) a gelling agent. The self-curable water-based solid adhesives of
the present invention can be applied with good workability, have good
fitting after attachment, have good adhesion to plastics, metals and
glass and exhibit excellent heat resistance and water resistance after
curing. They are highly safe to humans and the environment. They also
have excellent shape retention and slidability and can be easily applied.
In addition, they can bond adherends by contact bonding despite that they
are water-based solid adhesives. Accordingly, the self-curable
water-based solid adhesives of this invention are very useful as stick
adhesives.