This invention relates to a process for synthesizing
para-diisopropylbenzene utilizing only cumene and propylene as raw
materials. This synthesis technique offers the advantage of eliminating
benzene as a raw material used in the process. The elimination of benzene
is beneficial because it simplifies the process and eliminates the need
to purchase and store benzene for use in the synthesis. The elimination
of benzene from the synthesis is of particular value since the use of
benzene in industrial applications has been under attack on the basis of
environmental, safety, and health concerns. The present invention
discloses a process for producing para-diisopropylbenzene from cumene and
propylene, said process comprising the steps of (1) introducing a feed
stream into an alkylation zone wherein said feed stream is comprised of
cumene and propylene, and wherein said alkylation zone contains an
alkylation catalyst; (2) allowing the cumene and propylene in the feed
stream to react together to produce a first mixture of
para-diisopropylbenzene and meta-diisopropylbenzene; (3) fractionally
distilling the mixture of para-diisopropylbenzene and
meta-diisopropylbenzene in a fractional distillation step to separate the
meta-diisopropylbenzene from the para-diisopropylbenzene; (4) isomerizing
the meta-diisopropylbenzene in the presence of a transalkylation catalyst
to produce a second mixture of para-diisopropylbenzene and
meta-diisopropylbenzene; (5) recycling the second mixture of
para-diisopropylbenzene and meta-diisopropylbenzene recovered from the
transalkylation step to the fractional distillation step; and (6)
recovering the para-diisopropylbenzene that was separated from the
meta-diisopropylbenzene by the fractional distillation step.