Methods for controlling a melt viscosity of a polyolefin, controlling
comonomer distribution of a polyolefin, achieving a targeted melt
viscosity of a polyolefin, and films made from such polyolefins are
provided. The methods include contacting an olefin monomer and at least
one comonomer with a catalyst system in the presence of a condensable
fluid comprising a saturated hydrocarbon having from 2 to 8 carbon atoms.
The catalyst system in one embodiment includes a hafnium metallocene
catalyst component.