The present invention provides methods and apparatus for treating flue gas
containing sulfur dioxide using a scrubber, and more particularly relates
to recovering gypsum and magnesium hydroxide products from the scrubber
blowdown. The gypsum and magnesium hydroxide products are created using
two separate precipitation reactions. Gypsum is crystallized when
magnesium sulfate reacts with calcium chloride. Magnesium hydroxide is
precipitated when magnesium chloride from the gypsum crystallization
process reacts with calcium hydroxide. The process produces a high
quality gypsum with a controllable pH and particle size distribution, as
well as high quality magnesium hydroxide.