A multilayered article is disclosed, which includes, in sequence: (1) a
substrate (S), e.g., of thermoplastic polycarbonate; (2) a
scratch-resistant layer (SR); and (3) a top layer (T). The
scratch-resistant layer is prepared by curing a scratch-resistant coating
composition comprising a polycondensate prepared from at least one
silane, said polycondensate being prepared by a sol-gel process. The top
layer is prepared by curing a top layer coating composition prepared by
hydrolyzing a composition which includes: at lest one compound
represented by general formula I, M(R').sub.m (I) wherein M is an
element selected from the group consisting of Si, Ti, Zr, Sn, Ce, Al, B,
VO, In and Zn, R' represents a hydrolysable radical, and m is an integer
from 2 to 4; and optionally at least one compound represented by general
formula II, R.sub.bSiR'.sub.a, (II) wherein the radicals R' and R are
the same or different, R' is as defined for general formula (I), R
represents a group selected from an alkyl group, an alkenyl group, an
aryl group, a hydrocarbon group with at least one halogen group, an
epoxide group, a glycidyloxy group, an amino group, a mercapto group, a
methacryloxy group and a cyano group, and a and b independently of one
another have a value from 1 to 3, provided that the sum of a and b is
four. The multilayered articles are distinguished by possessing
outstanding scratch and abrasion resistance.