An ink set for ink-jet recording comprises a pigment ink and a dye ink containing a pigment and a dye as coloring agent, respectively. The pigment ink contains water, a water-soluble organic solvent, and a negatively charged pigment wherein potassium ion and sodium ion have a total ion concentration of not more than 200 ppm, and divalent or multivalent metal ion or ions have a total ion concentration of not more than 10 ppm. The dye ink contains water, a water-soluble organic solvent, and a dye associated with a counter ion of lithium ion wherein potassium ion and sodium ion have a total ion concentration of not more than 400 ppm, and divalent or multivalent metal ion or ions have a total ion concentration of not more than 10 ppm. In the ink set, the pigment and dye inks can be used in combination without complicating a maintenance system.