A process for the high-yield recovery of ethylene and heavier hydrocarbons
from the gas produced by pyrolysis of hydrocarbons in which the liquid
products resulting from the fractionated condensation of a cracking gas
for the recovery of almost all the ethylene, are supplied to a
distillation column, called a de-ethanizer, at different intermediate
levels. At the top of the de-ethanizer the vapor of the column distillate
is treated directly in an acetylene hydrogenation reactor, the effluent
containing virtually no acetylene being separated by a distillation
column called a de-methanizer, into an ethylene- and ethane-enriched tail
product, while the head product is recycled by compression or treated for
subsequent recovery of ethylene.