A stabilized catalyst support having improved hydrothermal stability,
catalyst made therefrom, and method for producing hydrocarbons from
synthesis gas using said catalyst. The stabilized support is made by a
method comprising treating a crystalline hydrous alumina precursor in
contact with at least one structural stabilizer or compound thereof. The
crystalline hydrous alumina precursor preferably includes an average
crystallite size selected from an optimum range delimited by desired
hydrothermal resistance and desired porosity. The crystalline hydrous
alumina precursor preferably includes an alumina hydroxide, such as
crystalline boehmite, crystalline bayerite, or a plurality thereof
differing in average crystallite sizes by at least about 1 nm. The
crystalline hydrous alumina precursor may be shaped before or after
contact with the structural stabilizer or compound thereof. The treating
includes calcining at 450.degree. C. or more. Preferred structural
stabilizers can include cobalt, magnesium, manganese, manganese,
zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof,
or combinations thereof.