An apparatus removes CO from a hydrogen-rich gas stream in a hydrogen fuel
cell system. CO fouls costly catalytic particles in the membrane
electrode assemblies. Both a catalyst adapted to perform a water gas
shift reaction, and a carbon dioxide adsorbent are disposed in a rotating
pressure swing adsorber housing. The adsorption of carbon dioxide shifts
equilibrium toward carbon monoxide consumption. A second adsorbent may be
disposed in the housing for adsorbing carbon monoxide at low
temperatures, and is adapted to desorb carbon monoxide at high
temperatures. The present invention advantageously eliminates a unit
operation from a space-constrained fuel cell vehicle by combining the WGS
catalyst and a CO.sub.2 adsorbent in a single reactor/housing. The
apparatus further eliminates the use of a PROX reactor, by providing an
apparatus which incorporates CO.sub.2 adsorption and consequent carbon
monoxide consumption in the place of the PROX reactor.