A method of fabrication of an electrooptical device comprises depositing a colloid system of anisometric particles onto at least one electrode and/or onto at least one substrate and/or onto at least one layer of an isotropic or anisotropic material to form at least one layer of an electrooptical material, externally aligning the colloid system to form a preferred alignment of the colloid system particles, drying the colloid system, and forming at least one electrode and/or at least one layer of an isotropic or anisotropic material on at least a portion of the layer of the electrooptical material.