An apparatus and method for processing hazardous wastes directly from
55-gallon drums through the use of pyrolysis and steam reforming. The
method is based on a pyrolyzer using heat to vaporize organics that are
present in the hazardous wastes. The waste is heated in the original
drums to avoid the bulk handling of alpha radionuclides and to ensure
criticality control. At pyrolysis temperatures, all liquids and organics
in the drums will evaporate and volatize. The resulting waste in the
drums is a dry, inert, inorganic matrix with carbon char containing
radioactive metals. The off-gas produced by pyrolysis mainly consists of
water vapor, volatized organics, and acid gases from the decomposition of
various plastics and other organics present in the waste drums. The
off-gas produced by the pyrolysis is then collected and fed into an
off-gas treatment system that is in fluid communication with pyrolyzer
operated under oxidizing conditions.