Fabrication apparatus and methods are disclosed for shaping and finishing
difficult materials with no subsurface damage. The apparatus and methods
use an atmospheric pressure mixed gas plasma discharge as a sub-aperture
polisher of, for example, fused silica and single crystal silicon,
silicon carbide and other materials. In one example, workpiece material
is removed at the atomic level through reaction with fluorine atoms. In
this example, these reactive species are produced by a noble gas plasma
from trace constituent fluorocarbons or other fluorine containing gases
added to the host argon matrix. The products of the reaction are gas
phase compounds that flow from the surface of the workpiece, exposing
fresh material to the etchant without condensation and redeposition on
the newly created surface. The discharge provides a stable and
predictable distribution of reactive species permitting the generation of
a predetermined surface by translating the plasma across the workpiece
along a calculated path.