The present invention provides a green catalytic process for the synthesis
of acetyl salicylic acid using solid acid catalysts at atmospheric
pressure. The invention involve the solid acid catalyst such as sulfated
transition metal oxides namely nano-crystalline sulfated zirconia,
sulfated titania; modified zeolites namely zeolite H-beta, H-Y, H-ZSM-5
and K-10 montmorillonite clay in a solvent free environment using
salicylic acid and acetic anhydride with yield about 95% and high
selectivity (100%). The solid acid catalysts can be recovered,
regenerated and reused.