A phosphate-free detergent formulation for machine dishwashing comprising,
as components: a) from 1 to 20% by weight of copolymers of a1) from 20
to 80% by weight, preferably from 30 to 70% by weight, of at least one
monomer from the group consisting of monoethylenically unsaturated
C.sub.3-C.sub.10-mono- or -dicarboxylic acids or anhydrides thereof, a2)
from 0 to 80% by weight, preferably from 10 to 50% by weight, of at least
one monomer of the general formula (I), ##STR00001## where
R.sup.1, R.sup.2 and R.sup.3 are each independently H, CH.sub.3 or
C.sub.2H.sub.5, R.sup.4 is a linear, branched or cyclic radical having
from 1 to 6 carbon atoms or an aromatic radical having from 6 to 12
carbon atoms, and a3) from 0 to 80% by weight, preferably from 5 to 20%
by weight, of at least one further monomer selected from the group
consisting of olefins having 10 or more carbon atoms or mixtures thereof
and reactive polyisobutenes having on average from 12 to 100 carbon
atoms, b) from 1 to 50% by weight of complexing agents, selected from
the group consisting of nitrilotriacetic acid,
hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetraacetic
acid, diethylenetriaminepentaacetic acid, methylglycinediacetic acid,
glutaminicaciddiacetic acid, iminodisuccinic acid, hydroxyiminodisuccinic
acid, ethylendiaminodisuccinic acid, asparaginicaciddiacetic acid and
salts therof, c) from 1 to 15% by weight of low-foaming nonionic
surfactants, d) from 0.1 to 30% by weight of bleaches and, if
appropriate, bleach activators, e) from 0 to 60% by weight of further
builders, f) from 0 to 8% by weight of enzymes, g) from 0 to 50% by
weight of one or more further additives such as anionic or zwitterionic
surfactants, bleach catalysts, alkali carriers, corrosion inhibitors,
defoamers, dyes, fragrances, fillers, organic solvents and water, the sum
of components a) to g) adding up to 100% by weight.