The lead-free optical glass can be used in the fields of imaging, sensor technology, microscopy, medical technology, digital projection, photolithography, laser technology, wafer/chip technology, as well as of telecommunications, optical communication engineering and optics/lighting in the automotive sector. It has a refractive index n.sub.d of 1.82.ltoreq.n.sub.d.ltoreq.2.00 and/or an Abbe number v.sub.d of 18.ltoreq.v.sub.d.ltoreq.28 with good chemical stability, excellent crystallization stability and the following composition, in wt. based on oxide content, of: TABLE-US-00001 P.sub.2O.sub.5 12-35 Nb.sub.2O.sub.5 30-50 Bi.sub.2O.sub.3 2-13 GeO.sub.2 0.1-7 Li.sub.2O .ltoreq.6 Na.sub.2O .ltoreq.6 K.sub.2O .ltoreq.6 Cs.sub.2O .ltoreq.6 MgO .ltoreq.6 CaO .ltoreq.6 SrO .ltoreq.6 BaO 7-<17 ZnO .ltoreq.6 TiO.sub.2 .ltoreq.7 ZrO.sub.2 .ltoreq.7 WO.sub.3 2-14 F .ltoreq.6.

 
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