Often NOx selective catalysts that use ammonia to reduce NOx within
exhaust to a harmless gas require on-board storage of ammonia which can
be hazardous and inconvenient. In order to generate ammonia in exhaust,
the present disclosure increases a NOx concentration in exhaust from at
least one combustion chamber, at least in part, by injecting fuel in a
predetermined increased NOx generation sequence that includes a first
injection during non-auto ignition conditions and a second injection
during auto ignition conditions. At least a portion of the NOx is
converted to ammonia by passing at least a portion of the exhaust with
the increased NOx concentration over an ammonia-producing catalyst.