Hydrogen production is provided via integrated closed-loop processing of
landfill gas (LFG) and solid biomass feedstocks such as various
agricultural wastes with minimal environmental impact. LFG is purified of
harmful contaminants over a bed of activated charcoal (AC) and is
catalytically reformed to synthesis gas, which is further processed to
pure hydrogen via CO-shift and pressure-swing adsorption stages. Biomass
is gasified in the presence of steam with production of a producer gas
and AC. The producer gas is mixed with LFG and is processed to hydrogen
as described above. High-surface area AC produced in the gasifier is used
for the purification of both LFG and producer gas. An integrated
processing of LFG and biomass offers a number of advantages such as a
high overall energy efficiency, feedstock flexibility, substantial
reduction in greenhouse gas emissions and production of value-added
product-biocarbon that can be used as a soil enhancer.