A method for polymerizing, in an aqueous medium, at least one fluorinated
monomer in the presence of a non-copolymerizable, non-fluorinated
surfactant. The surfactant is generally selected from a non-ionic
surfactant, a primary anionic surfactant, or a combination thereof.
Fluorinated surfactants are not utilized. The resulting partially
fluorinated polymer in the aqueous medium is either a semi-crystalline
polymer or a crystalline polymer.