A laminate of an air permeation preventive layer an adhesive layer provided with an air permeation preventive layer comprising a thermoplastic elastomer composition containing a thermoplastic resin as a continuous phase and a rubber composition dispersed therein as a dispersed phase and arranged on one surface of the air permeation preventive layer, an adhesive composition layer having a thickness of 100 .mu.m or less, a self tack of less than 5N and a tack to an unvulcanized diene-based rubber or 5N or more, containing 100 parts by weight of a thermoplastic elastomer containing 50 parts by weight or more of an epoxy-modified styrene-butadiene-based block copolymer so that a total of 30 to 200 parts by weight of a terpene resin and an aromatically modified terpene resin having a weight average molecular weight Mw of 1000 or less and a softening point of 60 to 120.degree. C., 0.1 to 3 parts by weight of an internal mold release agent and 0.1 to 2 parts by weight of an organic peroxide.