The present invention relates to a process for forming an organic electronic device having at least two organic layers. The process includes (a) applying a first organic layer having a first organic material by a method selected from vapor deposition and liquid deposition from a first organic liquid medium; (b) applying a second organic layer having a photoactive compound directly over at least a portion of the first organic layer by liquid deposition from a second organic liquid medium, wherein the first organic material is sparingly soluble in the second organic liquid medium.