Integrated process for preparing isocyanates

   
   

Process for preparing organic isocyanates, which comprises the steps

  • (a) making available a first partial amount of chlorine, with the chlorine of this first partial amount having a content of free and bound bromine and iodine of <400 ppm;
  • (b) making available a second partial amount of chlorine;
  • (c) reacting the first and second partial amounts of chlorine with carbon monoxide to form phosgene;
  • (d) reacting the phosgene from step (c) with one or more primary amines to form the corresponding isocyanates and hydrogen chloride;
  • (e) separating off and, if necessary, purifying the isocyanates formed in step (d);
  • (f) separating off and, if necessary, purifying the hydrogen chloride formed in step (d);
  • (g) catalytically oxidizing at least part of the hydrogen chloride separated off in step (e) by means of oxygen to form chlorine;
  • (h) separating off the chlorine formed in step (g) and using at least a partial amount of the chlorine which has been separated off as second partial amount of chlorine in step (b).
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