Aromatic polycarbonates are prepared by a process which includes a
continuous stage of oligomer preparation from a carbonyl halide such as
phosgene and a dihydroxyaromatic compound such as bisphenol A, under
interfacial conditions in the presence of an interfacial polycarbonate
formation catalyst and an alkali metal hydroxide. The molar ratio of
alkali metal hydroxide to carbonyl halide during oligomer preparation is
up to 1.8:1, preferably in the range of about 1.45-1.8:1. The oligomeric
intermediate product is then converted to high molecular weight
polycarbonate having a low proportion of cyclic oligomers, which improves
its thermodynamic stability.