The present invention relates to an all gas-phase process for the
purification of single-wall carbon nanotubes and the purified single-wall
carbon nanotube material. Known methods of single-wall carbon nanotube
production result in a single-wall carbon nanotube product that contains
single-wall carbon nanotubes in addition to impurities including residual
metal catalyst particles and amounts of small amorphous carbon sheets
that surround the catalyst particles and appear on the sides of the
single-wall carbon nanotubes and "ropes" of single-wall carbon nanotubes.
The purification process removes the extraneous carbon as well as
metal-containing residual catalyst particles. The process comprises
oxidation of the single-wall carbon nanotube material, reduction and
reaction of a halogen-containing gas with the metal-containing species.
The oxidation step may be done dry or in the presence of water vapor. The
present invention provides a scalable means for producing high-purity
single-wall carbon nanotube material.