The present invention is a new class of terpolymers for use as high strain
electrostrictive polymer films. More particularly, the invention is a
class of electrostrictive terpolymers comprising vinylidene fluoride
(VDF), trifluoroethylene (TrFE) and at least one monomer having at least
one halogen atom side group. The monomer is preferably an ethylene-based
monomer and preferably selected to favor gauche-type linkage along the
polymer backbone. The halogen atom side group is preferably large enough
to move or cause adjacent polymer chains to be farther apart from or away
from each other than in the absence of such side group, but not so large
that it would inhibit polymer crystallites from forming. The monomer is
preferably a chloro-monomer such as chlorofluoroethylene (CFE). The
chlorofluoroethylene (CFE) is preferably 1-chloro-2-fluoroethylene or
1-chloro-1-fluoroethylene. The chlorofluoroethylene (CFE) favors
gauche-type linkage which favors high electrostrictive strains.