A single step wet oxidation process for treating wastewaters containing
organic species, with or without heteroatoms, and anions of strong acids,
e.g. sulfate or phosphate ion, or cations of strong bases, e.g., sodium,
potassium or calcium ions, and which may contain ammonium ion and/or
nitrate ion in addition to added ammonium ion and/or nitrate ion was
developed which on thermal treatment near the critical temperature of
water removes substantially all the COD and nitrogen through conversion to
water, carbon dioxide or carbonate species, nitrogen gas and small amounts
of nitrous oxide. Key to the success of the process is the balancing of
all reducing species with an equivalent amount of oxidizing species and
the balancing of all strong acid anions with strong base cations. The
former ensures good removal of organic species, ammonium ion and nitrate
ion. The latter ensures maintaining the pH in the range of from 1.5 to 8
thus avoiding severe corrosion problems and regions of pH where rate of
reaction of the oxidizing species with reducing species is slow.